Phase Analysis of Australian Uranium Ore Concentrates Determined by Variable Temperature Synchrotron Powder X-ray Diffraction

The chemical speciation of uranium oxides is sensitive to the provenance of the samples and their storage conditions. Here, we use diffraction methods to characterize the phases found in three aged (>10 years) uranium ore concentrates of different origins as well as in situ analysis of the thermally induced structural transitions of these materials. The structures of the crystalline phases found in the three samples have been refined, using high-resolution synchrotron X-ray diffraction data. Rietveld analysis of the samples from the Olympic Dam and Ranger uranium mines has revealed the presence of crystalline α-UO2(OH)2, together with metaschoepite (UO2)4O(OH)6·5H2O, in the aged U3O8 samples, and it is speculated that this forms as a consequence of the corrosion of U3O8 in the presence of metaschoepite. The third sample, from the Beverley uranium mine, contains the peroxide [UO2(η2-O2)(H2O)2] (metastudtite) together with α-UO2(OH)2 and metaschoepite. A core–shell model is proposed to account for the broadening of the diffraction peaks of the U3O8 evident in the samples

Radionuclide and stable elements in flora from Australian arid environments

Dataset made available per the CC BY 4.0 Creative Commons Attribution 4.0 International license https://creativecommons.org/licenses/by/4.0/Radiological impact assessments are an important tool for energy and resources industries and government safety regulators to assist in the protection of wildlife diversity, especially native species. Evaluations of radiological impacts to flora in the arid regions of Australia are currently based on international models that use predominately Northern Hemisphere data, with very limited Australian-specific data. This creates a degree of uncertainty in communicating the potential impact of relevant Australian assessments. The project aims to build an improved understanding of radionuclide concentration ratios and radionuclide pathways in arid Australian conditions and are expected to inform assessments in similar environmental conditions elsewhere. The dataset contains measurement of stable elements and radionuclides in soils and plants that were obtained from three regions in South Australia: Flinders Ranges, Pernatty and Roxby Downs region. Access to Australian specific data for use in radiological impact models provide a better understanding and more credible environmental impact assessment process based on more relevant local information